Solid-Liquid Phase Equilibrium and Phase Behaviors for Binary Mixtures Composed of Tripalmitoylglycerol (PPP), 1,3-Dipalmitoyl-2-oleoyl-glycerol (POP), and 1,2-Dioleoyl-3-palmitoyl-glycerol (POO)

doi:10.1021/acs.iecr.9b01947

	Solid-Liquid Phase Equilibrium and Phase Behaviors for Binary Mixtures Composed of Tripalmitoylglycerol (PPP), 1,3-Dipalmitoyl-2-oleoyl-glycerol (POP), and 1,2-Dioleoyl-3-palmitoyl-glycerol (POO)
	Lu, Chao ; Zhang, Bo ; Zhang, Hua 2; Guo, Yun ; Dang, Leping ; Liu, Zhengan1 ; Shu, Qingyan 1; Wang, Zhanzhong
	2019
发表期刊	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN	0888-5885
卷号	58 期号:23 页码:10044-10052
摘要	The crystallization and melting behaviors of binary tripalmitoylglycerol (PPP)/1,2-dioleoyl-3-palmitoyl glycerol (P00), tripalmitoylglycerol (PPP)/1,3-dipalmitoy1-2-oleoyl glycerol (POP), and 1,3-dipalmitoyl-2-oleoyl glycerol (POP)/1,2dioleoy1-3-palmitoyl glycerol (P00) were investigated using differential scanning calorimetry (DSC). On the basis of melting phase equilibrium data, solid-liquid phase diagrams of binary systems (PPP/P00, PPP/POP, and POP/P00) were constructed. With respect to PPP/POO and PPP/POP, eutectic and solid solution phase equilibrium were confirmed when PPP content (X-PPP) in the mixtures was lower and higher than 90% and 80% (w/w), respectively. For POP/P00, the solid solution and eutectic phase equilibrium were confirmed when the POP content (X-POP) in the mixtures was lower and higher than 80% (w/w), respectively. Interestingly, polymorphic transition behaviors of PPP, POP, and POO at melting stages were also revealed. Finally, melting Gibbs free energy changes based on enthalpy changes for different binary mixtures were predicted by thermodynamics models.
学科领域	Engineering, Chemical
DOI	10.1021/acs.iecr.9b01947
收录类别	SCI
语种	英语
WOS关键词	DIFFERENTIAL SCANNING CALORIMETRY ; PALM OIL ; FATTY-ACIDS ; CRYSTALLIZATION ; TRIGLYCERIDES ; SYSTEMS
WOS研究方向	Engineering
WOS记录号	WOS:000471835000030
出版者	AMER CHEMICAL SOC
文献子类	Article
出版地	WASHINGTON
资助机构	National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21676196] ; Tianjin Municipal Natural Science FoundationNatural Science Foundation of Tianjin [17JCYBJC20400]
作者邮箱	shuqy@ibcas.ac.cn ; wzz7698@tju.edu.cn
引用统计	被引频次：13[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.ibcas.ac.cn/handle/2S10CLM1/19485
专题	中科院北方资源植物重点实验室
作者单位	1.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China 2.Chinese Acad Sci, Inst Bot, Beijing Bot Garden, Key Lab Plant Resources, Beijing 100093, Peoples R China 3.Chongqing Inst Food & Drug Control, Chongqing 401121, Peoples R China
推荐引用方式 GB/T 7714	Lu, Chao,Zhang, Bo,Zhang, Hua,et al. Solid-Liquid Phase Equilibrium and Phase Behaviors for Binary Mixtures Composed of Tripalmitoylglycerol (PPP), 1,3-Dipalmitoyl-2-oleoyl-glycerol (POP), and 1,2-Dioleoyl-3-palmitoyl-glycerol (POO)[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(23):10044-10052.
APA	Lu, Chao.,Zhang, Bo.,Zhang, Hua.,Guo, Yun.,Dang, Leping.,...&Wang, Zhanzhong.(2019).Solid-Liquid Phase Equilibrium and Phase Behaviors for Binary Mixtures Composed of Tripalmitoylglycerol (PPP), 1,3-Dipalmitoyl-2-oleoyl-glycerol (POP), and 1,2-Dioleoyl-3-palmitoyl-glycerol (POO).INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(23),10044-10052.
MLA	Lu, Chao,et al."Solid-Liquid Phase Equilibrium and Phase Behaviors for Binary Mixtures Composed of Tripalmitoylglycerol (PPP), 1,3-Dipalmitoyl-2-oleoyl-glycerol (POP), and 1,2-Dioleoyl-3-palmitoyl-glycerol (POO)".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.23(2019):10044-10052.

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