Knowledge Management System Of Institute Of Botany,CAS
| A transparent electrode with water-oxidizing activity | |
Azadi, Gouhar; Bagheri, Robabeh1; Bikas, Rahman2; Mousazade, Younes; Cui, Junfeng3,4; Song, Zhenlun1; Kinzhybalo, Vasyl5; Shen, Jian-Ren ; Allakhverdiev, Suleyman I.; Najafpour, Mohammad Mahdi14,15
| |
| 2018 | |
| 发表期刊 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| ISSN | 0360-3199 |
| 卷号 | 43期号:51页码:22896-22904 |
| 摘要 | Hydrogen production by water splitting is a promising method to store energy. Water-oxidation reaction is a bottleneck in water-splitting systems. Herein, a mononuclear nickel(II) phosphine complex with 1,2-bis(dicyclohexylphosphino)ethane ligand, was synthesized and characterized by X-ray crystallography method. The water-oxidizing catalyst under the electrochemical condition was studied. The role of Ni compound for the water-oxidation reaction on the surface of fluorine-doped tin oxide as one of the true catalysts was investigated by the electrochemical methods and Scanning Electron Microscopy coupled with Energy Dispersive X-ray (SEM/EDX) Spectroscopy. The big ligand around the Ni ion causes a very small size of Ni-based particles on the surface of the electrode, which are the active catalysts for the water-oxidation reaction. Such small nanosized Ni-based compounds are transparent and have no effect on the transparency of the obtained fluorine-doped tin oxide. Thus, it is a promising method to synthesize a transparent fluorine-doped tin oxide with water-oxidizing activity. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
| 关键词 | Water oxidation Hydrogen production Fluorine-doped tin oxide Catalyst |
| 学科领域 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
| DOI | 10.1016/j.ijhydene.2018.10.146 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS关键词 | OXIDATION CATALYSTS ; SINGLE-CRYSTALS ; MANGANESE OXIDE ; NICKEL ; COMPLEX ; EFFICIENT ; TETRAFLUOROBORATE ; ELECTROCATALYSTS ; PALLADIUM ; INSIGHTS |
| WOS记录号 | WOS:000453642500011 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 文献子类 | Article |
| 出版地 | OXFORD |
| EISSN | 1879-3487 |
| 资助机构 | Iran National Science Foundation (INSF)Iran National Science Foundation (INSF) [95007330] ; Institute for Advanced Studies in Basic Sciences, Imam Khomeini International University ; Polish Academy of Science [24000018] ; JSPS, MEXT, JapanMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science [24000018] ; Russian Science FoundationRussian Science Foundation (RSF) [14-14-00039] |
| 作者邮箱 | suleyman.allakhverdiiev@gmail.com ; mmnajafpour@iasbs.ac.ir |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.ibcas.ac.cn/handle/2S10CLM1/20616 |
| 专题 | 中科院光生物学重点实验室 |
| 作者单位 | 1.IASBS, Dept Chem, Zanjan 4513766731, Iran 2.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Surface Dept, Surface Protect Res Grp, 519 Zhuangshi Rd, Ningbo 315201, Zhejiang, Peoples R China 3.Imam Khomeini Int Univ, Dept Chem, Fac Sci, Qazvin 3414896818, Iran 4.Dalian Univ Technol, Key Lab Precis & Nontradit Machining Technol, Minist Educ, Dalian 116024, Peoples R China 5.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China 6.Polish Acad Sci, Inst Low Temp & Struct Res, PL-50422 Wroclaw, Poland 7.Okayama Univ, Res Inst Interdisciplinary Sci, Okayama 7008530, Japan 8.Okayama Univ, Grad Sch Nat Sci & Technol, Okayama 7008530, Japan 9.Chinese Acad Sci, Inst Bot, Photosynth Res Ctr, Key Lab Photobiol, 20 Nanxincun, Beijing 100093, Peoples R China 10.Allakhverdiev, Suleyman I.] Russian Acad Sci, Inst Plant Physiol, Controlled Photobiosynth Lab, Bot Skaya St 35, Moscow 127276, Russia 11.Allakhverdiev, Suleyman I.] Azerbaijan Natl Acad Sci, Inst Mol Biol & Biotechnol, Bionanotechnol Lab, Matbuat Ave 2a, Baku 1073, Azerbaijan 12.Allakhverdiev, Suleyman I.] Russian Acad Sci, Inst Basic Biol Problems, Pushchino 142290, Moscow Region, Russia 13.Allakhverdiev, Suleyman I.] Moscow MV Lomonosov State Univ, Dept Plant Physiol, Fac Biol, Leninskie Gory 1-12, Moscow 119991, Russia 14.Allakhverdiev, Suleyman I.] Moscow Inst Phys & Technol, Inst Sky Lane 9, Dolgoprudnyi 141700, Moscow Region, Russia 15.IASBS, Ctr Climate Change & Global Warming, Zanjan 4513766731, Iran 16.IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran |
| 推荐引用方式 GB/T 7714 | Azadi, Gouhar,Bagheri, Robabeh,Bikas, Rahman,et al. A transparent electrode with water-oxidizing activity[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2018,43(51):22896-22904. |
| APA | Azadi, Gouhar.,Bagheri, Robabeh.,Bikas, Rahman.,Mousazade, Younes.,Cui, Junfeng.,...&Najafpour, Mohammad Mahdi.(2018).A transparent electrode with water-oxidizing activity.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,43(51),22896-22904. |
| MLA | Azadi, Gouhar,et al."A transparent electrode with water-oxidizing activity".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 43.51(2018):22896-22904. |
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| 1-s2.0-S036031991833（2924KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 浏览 请求全文 | |
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论