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| An aluminum/cobalt/iron/nickel alloy as a precatalyst for water oxidation | |
Najafpour, Mohammad Mandi1,2; Mehrabani, Somayeh; Bagheri, Robabeh3; Song, Zhenlun3; Shen, Jian-Ren ; Allakhverdiev, Suleyman I.
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| 2018 | |
| 发表期刊 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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| ISSN | 0360-3199 |
| 卷号 | 43期号:4页码:2083-2090 |
| 摘要 | Among different strategies, water splitting toward hydrogen production is a promising process to store energy from intermittent sources. However, the anodic water oxidation is a bottleneck for water splitting. In this paper, we report an aluminum/cobalt/iron/nickel alloy as a precatalyst for the electrochemical water oxidation. The alloy electrode contains different metal ions including cobalt, iron, and nickel which all are efficient for water oxidation is tested. We characterized this electrode using scanning electron microscopy, transmission electron microscopy, diffuse reflectance infrared Fourier transform spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy and electrochemical methods. After stabilization, the electrode shows an onset overpotential of 200.0 mV and affords a current density of 3.5 mA cm(-2) at an overpotential of 600.0 mV in KOH solution at pH 13. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
| 关键词 | Alloy Artificial photosynthesis Hydrogen production Water Water-oxidizing catalyst Water oxidation |
| 学科领域 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
| DOI | 10.1016/j.ijhydene.2017.12.025 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS关键词 | CATALYST COATED MEMBRANES ; ARTIFICIAL PHOTOSYNTHESIS ; OXIDIZING CATALYSTS ; HYDROGEN-PRODUCTION ; MANGANESE COMPOUNDS ; FATIGUE ; PHOTOCATALYST ; SIMULATION ; EVOLUTION ; COMPLEX |
| WOS记录号 | WOS:000424725100015 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 文献子类 | Article |
| 出版地 | OXFORD |
| EISSN | 1879-3487 |
| 资助机构 | Institute for Advanced Studies in Basic Sciences ; National Elite Foundation ; RFBR-INSF ; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [17-54-56 0012] ; Iran National Science FoundationIran National Science Foundation (INSF) [96003636] |
| 作者邮箱 | mmnajafpour@iasbs.ac.ir ; suleyman.allakhverdiev@gmail.com |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.ibcas.ac.cn/handle/2S10CLM1/20629 |
| 专题 | 中科院光生物学重点实验室 |
| 作者单位 | 1.IASBS, Dept Chem, Zanjan 4513766731, Iran 2.IASBS, Ctr Climate Change & Global Warming, Zanjan 4513766731, Iran 3.IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran 4.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Surface Dept, Surface Protect Res Grp, 519 Zhuangshi Rd, Ningbo 315201, Zhejiang, Peoples R China 5.Okayama Univ, Res Inst Interdisciplinary Sci, Okayama 7008530, Japan 6.Okayama Univ, Grad Sch Nat Sci & Technol, Okayama 7008530, Japan 7.Chinese Acad Sci, Inst Bot, Key Lab Photobiol, Photosynth Res Ctr, 20,Nanxincun, Beijing 100093, Peoples R China 8.Allakhverdiev, Suleyman I.] Russian Acad Sci, Inst Plant Physiol, Controlled Photobiosynth Lab, Bot Skaya St 35, Moscow 127276, Russia 9.Allakhverdiev, Suleyman I.] Russian Acad Sci, Inst Basic Biol Problems, Inst Skaya St 2, Pushchino 142290, Moscow Region, Russia 10.Allakhverdiev, Suleyman I.] Moscow MV Lomonosov State Univ, Fac Biol, Dept Plant Physiol, Leninskie Gory 1-12, Moscow 119991, Russia 11.Allakhverdiev, Suleyman I.] Moscow Inst Phys & Technol, Inst Sky Lane 9, Dolgoprudnyi 141700, Moscow Region, Russia 12.Allakhverdiev, Suleyman I.] Azerbaijan Natl Acad Sci, Inst Mol Biol & Biotechnol, Bionanotechnol Lab, Matbuat Ave 2a, Baku 1073, Azerbaijan |
| 推荐引用方式 GB/T 7714 | Najafpour, Mohammad Mandi,Mehrabani, Somayeh,Bagheri, Robabeh,et al. An aluminum/cobalt/iron/nickel alloy as a precatalyst for water oxidation[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2018,43(4):2083-2090. |
| APA | Najafpour, Mohammad Mandi,Mehrabani, Somayeh,Bagheri, Robabeh,Song, Zhenlun,Shen, Jian-Ren,&Allakhverdiev, Suleyman I..(2018).An aluminum/cobalt/iron/nickel alloy as a precatalyst for water oxidation.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,43(4),2083-2090. |
| MLA | Najafpour, Mohammad Mandi,et al."An aluminum/cobalt/iron/nickel alloy as a precatalyst for water oxidation".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 43.4(2018):2083-2090. |
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| 1-s2.0-S036031991734（4540KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 浏览 请求全文 | |
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